Champions League predictions – Chelsea, Liverpool, Man City, Spurs GW1 chances calculated
Liverpool, looking to defend their crown, have perhaps the toughest trip of all as they head to Napoli.
Jurgen Klopp watched his side lost this fixture last term courtesy of a late Lorenzo Insigne goal.
The geniuses at FiveThiryEight have calculated the likeliness of each team winning, losing or simply picking up a point.
The Reds have been given a 43 per cent chance of winning despite their daunting trip, but are yet to taste defeat this season.
City face the unenviable task of a trip to eastern Europe to take on Shakhtar Donesk, but can take confidence from winning this fixture last term.
They have a 60 per cent chance of winning in Ukraine before heading back to Manchester to prepare for the visit of Watford.
City will be under pressure to perform and get back to winning ways following their surprise loss at Norwich on Saturday evening.
Last season’s finalists Tottenham romped to victory over Crystal Palace at the weekend to give them the ideal preparation.
They head to the Greek capital to take on Olympiakos and are marginal favourites with a 38 per cent chance of victory to their opponents 37 per cent.
Frank Lampard takes his managerial bow in European competition but his Blues side are heavy favourites to win with a 58% of victory.
The Spanish side recently sacked their manager and head to London after being humbled at the Nou Camp.